In LINQ, the OrderByDescending operator is used to sort the list/collection of items in descending order.
Syntax of LINQ OrderByDescending Operator
Following is the syntax of using the LINQ orderbydescending operator to sort the list of item values in descending order.
 LINQ OrderByDescending Syntax in C# 
var studentname = Objstudent.OrderByDescending(x => x.Name);
LINQ OrderByDescending Syntax in VB.NET 
Dim studentname = Objstudent.OrderByDescending(Function(x) x.Name)
If you observe above syntax we are sorting Objstudent collection items using linq OrderByDescending operator. 
LINQ OrderByDescending Operator Example
Following is the example of using the LINQ orderbydescending sorting operator to sort the list of items in descending order.
LINQ OrderByDescending Example in C#
using System;
 using System.Collections.Generic;
 using System.Linq;
 namespace LINQExamples
 {
   class Program
   {
      static void Main(string[] args)
      {
         List<Student> Objstudent = new List<Student>()
         {
            new Student() { Name = "Suresh Dasari", Gender = "Male", Subjects = new List<string> { "Mathematics", "Physics" } },
            new Student() { Name = "Rohini Alavala", Gender = "Female", Subjects = new List<string> { "Entomology", "Botany" } },
            new Student() { Name = "Praveen Kumar", Gender = "Male", Subjects = new List<string> { "Computers", "Operating System", "Java" } },
            new Student() { Name = "Sateesh Chandra", Gender = "Male", Subjects = new List<string> { "English", "Social Studies", "Chemistry" } },
            new Student() { Name = "Madhav Sai", Gender = "Male", Subjects = new List<string> { "Accounting", "Charted" } }
         };
         var studentname = Objstudent.OrderByDescending(x => x.Name);
         foreach (var student in studentname)
         {
            Console.WriteLine(student.Name);
         }
         Console.ReadLine();
      }
   }
   class Student
   {
     public string Name { get; set; }
     public string Gender { get; set; }
     public List<string> Subjects { get; set; }
   }
 }
LINQ OrderByDescending Example in VB.NET
Module Module1
 Sub Main()
 Dim Objstudent As New List(Of Student)() From {
 New Student() With {.Name = "Suresh Dasari", .Gender = "Male", .Subjects = New List(Of String)() From {"Mathematics", "Physics"}},
 New Student() With {.Name = "Rohini Alavala", .Gender = "Female", .Subjects = New List(Of String)() From {"Entomology", "Botany"}},
 New Student() With {.Name = "Praveen Kumar", .Gender = "Male", .Subjects = New List(Of String)() From {"Computers", "Operating System", "Java"}},
 New Student() With {.Name = "Sateesh Chandra", .Gender = "Male", .Subjects = New List(Of String)() From {"English", "Social Studies", "Chemistry"}},
 New Student() With {.Name = "Madhav Sai", .Gender = "Male", .Subjects = New List(Of String)() From {"Accounting", "Charted"}}
 }
 Dim studentname = Objstudent.OrderByDescending(Function(x) x.Name)
 For Each student In studentname
 Console.WriteLine(student.Name)
 Next
 Console.ReadLine()
 End Sub
 Class Student
 Public Property Name() As String
 Get
 Return m_Name
 End Get
 Set(ByVal value As String)
 m_Name = value
 End Set
 End Property
 Private m_Name As String
 Public Property Gender() As String
 Get
 Return m_Gender
 End Get
 Set(ByVal value As String)
 m_Gender = value
 End Set
 End Property
 Private m_Gender As String
 Public Property Subjects() As List(Of String)
 Get
 Return m_Subjects
 End Get
 Set(ByVal value As List(Of String))
 m_Subjects = value
 End Set
 End Property
 Private m_Subjects As List(Of String)
 End Class
 End Module
The above example shows that we used the OrderByDescending operator to sort list items in descending order.
Result of LINQ OrderByDescending Operator
Following is the result of using the LINQ OrderByDescending operator to sort list items in descending order.
 
Suresh Dasari
 Sateesh Chandra
 Rohini Alavala
 Praveen Kumar
 Madhav Sai
This is how we can use LINQ orderbydescending operator to sort the list of items in descending order.